Sains Malaysiana 53(10)(2024): 3279-3288
            
          
          http://doi.org/10.17576/jsm-2024-5310-04
            
          
          
             
          
          Komposisi Isotop Radiogenik Pb
            Longgokan Emas Orogeni Bufffalo Reef, Pahang, Malaysia: Implikasi terhadap
            Genesis Bijih
            
          
          (Radiogenic Pb Isotope Composition of
            the Buffalo Reef Orogenic Gold Deposit, Pahang, Malaysia: Implications for Ore
            Genesis)
              
          
          
            
          
          MAZLINFALINA MOHD ZIN1,*,
            MOHD BASRIL ISWADI BASORI1, HABIBAH JAMIL1 &
            NASIRUDIN YUSOFF2
  
          
             
          
          1Jabatan Sains Bumi dan Alam Sekitar, Fakulti Sains dan Teknologi,
            Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia
            
          
          2Pejabat Dekan, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia,
            43600 UKM Bangi, Selangor, Malaysia
            
          
          
             
          
          Received:
            19 May 2024/Diterima: 11 Accepted 2024
  
          
          
             
          
          Abstrak
            
          
          Longgokan emas Buffalo Reef di Jalur Tengah Semenanjung Malaysia merupakan
            longgokan jenis orogeni yang berkongsi banyak cirian geologi dengan longgokan
            emas orogeni lain di rantau ini. Batuan perumah di Buffalo Reef didominasi oleh
            batuan sedimen iaitu syal, syal berkarbon, batu lodak, batu lumpur, batuan
            metamorf gred rendah (sabak) dan batuan volkanik.   Komposisi isotop Pb bagi sulfida di dalam
            telerang kuarza dan batuan perumah daripada longgokan emas Buffalo Reef
            dilaporkan dalam kajian ini sebagai salah satu kaedah untuk menentukan sumber
            larutan pembentuk bijih, julat sempadan usia (modal age) dan sekitaran tektonik. Hasil kajian ini kemudiannya
            disepadukan dengan gambaran keseluruhan sekitaran geodinamik serantau, untuk
            lebih memahami tentang genesis longgokan emas orogeni di rantau ini. Empat
            mineral stibnit di dalam telerang kuarza memberikan julat nisbah 206Pb/204Pb daripada 18.5953 hingga 18.6318, nisbah 207Pb/204Pb antara 15.6564 dan 15.6910 dan nisbah 208Pb/204Pb sekitar 38.6378 hingga 38.7503. Sementara itu, nisbah untuk 206Pb/204Pb, 207Pb/204Pb dan 208Pb/204Pb bagi satu mineral stibnit daripada batuan perumah ialah 18.6215, 15.6242 dan 38.6132. Secara keseluruhannya, nilai data isotop Pb yang terkandung oleh mineral stibnit di dalam telerang kuarza adalah agak kecil dan menunjukkan persamaan dengan nilai isotop Pb yang terkandung oleh mineral stibnit di dalam batuan perumah. Hasil kajian menunjukkan bahawa sumber utama Pb dalam larutan hidroterma pemineralan di Buffalo Reef berasal daripada percampuran Pb kerak atas dengan Pb daripada sumber igneus/mantel yang terbentuk di sekitaran tektonik subduksi-perlanggaran yang membentuk jalur orogeni. Perbandingan data isotop Pb dalam longgokan emas Buffalo Reef dengan beberapa longgokan emas orogeni di Semenanjung Malaysia menunjukkan nilai isotop Pb dan sekitaran tektonik yang konsisten dan seragam serta semuanya berada dalam julat umur modal 0-200 juta tahun. Penemuan ini selaras dengan kejadian longgokan emas orogeni di Buffalo Reef dan longgokan emas orogeni lain di rantau ini yang terbentuk terutamanya di sepanjang sempadan kerak menumpu bagi jalur orogeni perlanggaran.
            
            
          
             
          
          Kata kunci: Buffalo Reef; emas orogeni;
            genesis; isotop Pb; Semenanjung Malaysia
            
          
          
             
          
          Abstract
            
          
          The Buffalo Reef gold deposit in the Central Belt of
            Peninsular Malaysia is an orogenic deposit type that shares many geologic
            features with other orogenic gold deposits in this region. The host rocks in
            the Buffalo Reef are dominated by sedimentary rocks, which are shale,
            carbonaceous shale, siltstone, mudstone, low-grade metamorphic rock (slate),
            and volcanic rocks. The Pb isotope compositions of sulfides in quartz veins and
            host rocks from the Buffalo Reef deposit are reported in this study as an
            attempt to constrain the source of the ore-forming fluids, modal age and
            tectonic setting. These results are then integrated with an overview of the
            regional geodynamic setting to advance understanding of the genesis of the
            orogenic gold deposits in this region. Four stibnite minerals in quartz veins yield 206Pb/204Pb ratios ranging
              from 18.5953 to 18.6318, 207Pb/204Pb ratios between
              15.6564 and 15.6910, and 208Pb/204Pb ratios around
              38.6378 to 38.7503. Meanwhile, the 206Pb/204Pb, 207Pb/204Pb,
              and 208Pb/204Pb ratios for one stibnite mineral from the
              host rock are 18.6215, 15.6242, and 38.6132, respectively. Overall, the
              isotopic Pb data values contained by the stibnite mineral in quartz veins are
              relatively small and exhibit consistency with the isotopic Pb values contained
              by the stibnite mineral in the host rock. The results suggest that the primary source of Pb in the
                hydrothermal mineralizing solution at Buffalo Reef originates from the mixing
                of Pb from the upper crust with Pb from igneous/mantle sources formed in the
                vicinity of subduction-collision tectonic settings that form orogenic belts. Comparison of Pb isotopic data in
                  the Buffalo Reef deposit with several orogenic gold deposits in Peninsular
                  Malaysia shows a consistent and uniform pattern of Pb isotopic values and
                  tectonic settings, all falling within the modal ages range of 0-200 million years. These findings are consistent with the
                    formation of the orogenic gold deposit at Buffalo Reef and other orogenic gold
                    deposits in the
                      region that form primarily along convergent plate
                        margins of the collisional orogenic belt.
  
          
             
          
          Keywords: Buffalo Reef; genesis; Pb isotope; Peninsular Malaysia; orogenic
            gold
            
          
          
             
          
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          *Corresponding
            author; email: farlinnzin@gmail.com